The generic structural formula for a 1-alkyl-3-methyli
Question and Solution
The generic structural formula for a 1-alkyl-3-methylimidazolium cation is Where R is a Â¬CH2(CH2)nCH3 alkyl group.
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The generic structural formula for a 1-alkyl-3-methylimidazolium cation is Where R is a Â¬CH2(CH2)nCH3 alkyl group. The melting points of the salts that form between the 1-alkyl-3-methylimidazolium cation and the PF6- anion are as follows: R = CH2CH3 (m.p. 60 Â°C), R CH2CH2CH3 (m.p. 40 Â°C), R= CH2CH2CH2CH3 (m.p. 10 Â°C) and R = CH2CH2CH2CH2CH2CH3(m.p. = - 61 oC). Why does the melting point decrease as the length of alkyl group increases?
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